{"id":492,"date":"2023-05-14T18:09:04","date_gmt":"2023-05-14T16:09:04","guid":{"rendered":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/?page_id=492"},"modified":"2023-05-14T18:09:57","modified_gmt":"2023-05-14T16:09:57","slug":"anna-lena-schone","status":"publish","type":"page","link":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/anna-lena-schone\/","title":{"rendered":"Anna Lena Sch\u00f6ne, M.Sc."},"content":{"rendered":"<p>Researcher<\/p>\n\n\n\n<div class=\"wp-block-columns is-layout-flex wp-container-core-columns-is-layout-9d6595d7 wp-block-columns-is-layout-flex\">\n<div class=\"wp-block-column is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:66.66%\">\n<p><strong>Address<\/strong><br>Ruhr-Uni\u00adver\u00adsi\u00adt\u00e4t Bo\u00adchum<br>Fakult\u00e4t f\u00fcr Elektrotechnik und Informationstechnik<br>Biomedizinsch Angewandte Plasmatechnik<br>Uni\u00adver\u00adsi\u00adt\u00e4ts\u00adstra\u00ad\u00dfe 150<br>D-44801 Bo\u00adchum, Germany<\/p>\n\n\n\n<p><strong>Room<\/strong><br>ID 1\/531<\/p>\n\n\n\n<p><strong>Phone<\/strong><br>+49 234 32 28872<\/p>\n\n\n\n<p><strong>Email<\/strong><br>schoene(at)aept.rub.de<\/p>\n<\/div>\n\n\n\n<div class=\"wp-block-column is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:33.33%\">\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"682\" height=\"1024\" src=\"https:\/\/aept.blogs.ruhr-uni-bochum.de\/wp-content\/uploads\/2023\/05\/AnnaLena-Schoene-WEB-00435-sRGB-682x1024.jpg\" alt=\"\" class=\"wp-image-359\" srcset=\"https:\/\/aept.blogs.ruhr-uni-bochum.de\/wp-content\/uploads\/2023\/05\/AnnaLena-Schoene-WEB-00435-sRGB-682x1024.jpg 682w, https:\/\/aept.blogs.ruhr-uni-bochum.de\/wp-content\/uploads\/2023\/05\/AnnaLena-Schoene-WEB-00435-sRGB-200x300.jpg 200w, https:\/\/aept.blogs.ruhr-uni-bochum.de\/wp-content\/uploads\/2023\/05\/AnnaLena-Schoene-WEB-00435-sRGB-768x1152.jpg 768w, https:\/\/aept.blogs.ruhr-uni-bochum.de\/wp-content\/uploads\/2023\/05\/AnnaLena-Schoene-WEB-00435-sRGB.jpg 853w\" sizes=\"auto, (max-width: 682px) 100vw, 682px\" \/><\/figure>\n<\/div>\n<\/div>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity is-style-wide\"\/>\n\n\n\n<p><strong>Publications<\/strong><\/p>\n\n\n<div id=\"zotpress-e25db87b6c5a5ee0743d30983e7a4d9c\" class=\"zp-Zotpress zp-Zotpress-Bib wp-block-group\">\n\n\t\t<span class=\"ZP_API_USER_ID ZP_ATTR\">2825793<\/span>\n\t\t<span class=\"ZP_ITEM_KEY ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_COLLECTION_ID ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_TAG_ID ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_AUTHOR ZP_ATTR\">Sch\u00f6ne<\/span>\n\t\t<span class=\"ZP_YEAR ZP_ATTR\"><\/span>\n        <span class=\"ZP_ITEMTYPE ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_INCLUSIVE ZP_ATTR\">1<\/span>\n\t\t<span class=\"ZP_STYLE ZP_ATTR\">apa<\/span>\n\t\t<span class=\"ZP_LIMIT ZP_ATTR\">50<\/span>\n\t\t<span class=\"ZP_SORTBY ZP_ATTR\">date<\/span>\n\t\t<span class=\"ZP_ORDER ZP_ATTR\">desc<\/span>\n\t\t<span class=\"ZP_TITLE ZP_ATTR\">year<\/span>\n\t\t<span class=\"ZP_SHOWIMAGE ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_SHOWTAGS ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_DOWNLOADABLE ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_NOTES ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_ABSTRACT ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_CITEABLE ZP_ATTR\">1<\/span>\n\t\t<span class=\"ZP_TARGET ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_URLWRAP ZP_ATTR\"><\/span>\n\t\t<span class=\"ZP_FORCENUM ZP_ATTR\"><\/span>\n        <span class=\"ZP_HIGHLIGHT ZP_ATTR\">Sch&ouml;ne<\/span>\n        <span class=\"ZP_POSTID ZP_ATTR\">492<\/span>\n\t\t<span class=\"ZOTPRESS_PLUGIN_URL ZP_ATTR\">https:\/\/aept.blogs.ruhr-uni-bochum.de\/wp-content\/plugins\/zotpress\/<\/span>\n\n\t\t<div class=\"zp-List loading\">\n\t\t\t<div class=\"zp-SEO-Content\">\n\t\t\t\t<span class=\"ZP_JSON ZP_ATTR\">%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3Afalse%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22RWLZGH2K%22%2C%22library%22%3A%7B%22id%22%3A2825793%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Grimm%20et%20al.%22%2C%22parsedDate%22%3A%222026-01-23%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%202%3B%20padding-left%3A%201em%3B%20text-indent%3A-1em%3B%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%26gt%3BGrimm%2C%20F.%2C%20Gembus%2C%20J.-L.%2C%20Sch%26%23xF6%3Bne%2C%20J.%2C%20Awakowicz%2C%20P.%2C%20Sch%26%23xFC%3Bcke%2C%20L.%2C%20%26amp%3B%20Gibson%2C%20A.%20R.%20%282026%29.%20Electron%20and%20gas%20temperature-driven%20chemistry%20during%20microdischarges%20formed%20in%20water%20vapor%20bubbles.%20%26lt%3Bi%26gt%3BJournal%20of%20Physics%20D%3A%20Applied%20Physics%26lt%3B%5C%2Fi%26gt%3B%2C%20%26lt%3Bi%26gt%3B59%26lt%3B%5C%2Fi%26gt%3B%283%29%2C%20035201.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fae20a1%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fae20a1%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D2825793%26amp%3Bitem_key%3DRWLZGH2K%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electron%20and%20gas%20temperature-driven%20chemistry%20during%20microdischarges%20formed%20in%20water%20vapor%20bubbles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florens%22%2C%22lastName%22%3A%22Grimm%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jan-Luca%22%2C%22lastName%22%3A%22Gembus%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jana%22%2C%22lastName%22%3A%22Sch%5Cu00f6ne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peter%22%2C%22lastName%22%3A%22Awakowicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lars%22%2C%22lastName%22%3A%22Sch%5Cu00fccke%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrew%20R%22%2C%22lastName%22%3A%22Gibson%22%7D%5D%2C%22abstractNote%22%3A%22Microdischarges%20formed%20in%20bubbles%20immersed%20in%20liquids%20are%20of%20interest%20for%20materials%20synthesis%20and%20chemical%20conversion%20applications%20in%20the%20frame%20of%20plasma-driven%20electrochemistry.%20A%20key%20challenge%20associated%20with%20controlling%20such%20processes%20is%20the%20limited%20understanding%20of%20the%20gas-phase%20chemical%20kinetics%20in%20these%20microdischarges.%20Due%20to%20their%20large%20electron%20densities%2C%20and%20high%20gas%20temperatures%2C%20both%20electron%20and%20gas%20temperature-driven%20chemistry%20are%20likely%20to%20be%20important.%20Here%2C%20a%200-D%20modeling%20approach%2C%20informed%20by%20experimental%20measurements%2C%20is%20used%20to%20study%20the%20chemical%20kinetics%20in%20these%20systems.%20A%20new%20reaction%20scheme%20is%20developed%20for%20microdischarges%20in%20water%20vapor%2C%20including%20reactions%20for%20both%20high%20electron%20density%2C%20and%20high%20gas%20temperature%20regimes.%20Microdischarges%20formed%20during%20plasma%20electrolytic%20oxidation%20are%20used%20as%20a%20test%20case%2C%20however%2C%20the%20key%20results%20are%20expected%20to%20be%20transferable%20to%20other%20plasma%20electrolysis%20systems%20with%20similar%20properties.%20Experimentally%20measured%20power%20densities%20are%20used%20as%20input%20to%20the%200-D%20model%2C%20together%20with%20estimates%20of%20temperatures%20and%20gas%20pressures%20within%20the%20gas%20bubble.%20Comparison%20of%20measured%20and%20simulated%20electron%20densities%20shows%20good%20agreement%2C%20given%20the%20limitations%20of%20both%20model%20and%20experiment.%20In%20the%20base%20case%20microdischarge%2C%20H2O%20is%20found%20to%20be%20highly%20dissociated%20during%20the%20period%20of%20peak%20power%20density%2C%20with%20H%20and%20O%20making%20up%20the%20majority%20of%20the%20neutral%20gas%20in%20the%20bubble.%20The%20maximum%20ionization%20degree%20is%20around%200.31%25%2C%20and%20the%20electronegativity%20during%20the%20period%20of%20peak%20electron%20density%20is%20found%20to%20be%20low.%20Species%20formation%20and%20reaction%20pathways%20are%20analyzed%20under%20variation%20of%20the%20neutral%20gas%20temperature%20from%202000%20K%20to%206000%20K.%20At%20all%20temperatures%2C%20electron%2C%20ion%2C%20and%20neutral%20reactions%20with%20high%20threshold%20energies%20are%20found%20to%20be%20important%20for%20the%20overall%20chemical%20kinetics.%22%2C%22date%22%3A%222026-01-23%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-6463%5C%2Fae20a1%22%2C%22citationKey%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2Farticle%5C%2F10.1088%5C%2F1361-6463%5C%2Fae20a1%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220022-3727%2C%201361-6463%22%2C%22language%22%3A%22en%22%2C%22collections%22%3A%5B%5D%2C%22dateModified%22%3A%222026-01-19T14%3A50%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22I5FKP9A4%22%2C%22library%22%3A%7B%22id%22%3A2825793%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sch%5Cu00f6ne%20et%20al.%22%2C%22parsedDate%22%3A%222025-09-15%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%202%3B%20padding-left%3A%201em%3B%20text-indent%3A-1em%3B%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%26gt%3BSch%26%23xF6%3Bne%2C%20A.%20L.%2C%20Sch%26%23xFC%3Bttler%2C%20S.%2C%20Mro%26%23xDF%3B%2C%20T.%2C%20Eichstaedt%2C%20N.%2C%20Golda%2C%20J.%2C%20Sch%26%23xFC%3Bcke%2C%20L.%2C%20%26amp%3B%20Gibson%2C%20A.%20R.%20%282025%29.%20Concentration%20profiles%20of%20OH%20and%20H%26lt%3Bsub%26gt%3B2%26lt%3B%5C%2Fsub%26gt%3B%20O%26lt%3Bsub%26gt%3B2%26lt%3B%5C%2Fsub%26gt%3B%20in%20plasma-treated%20water%3A%20influence%20of%20power%2C%20gas%20mixture%20and%20treatment%20distance.%20%26lt%3Bi%26gt%3BJournal%20of%20Physics%20D%3A%20Applied%20Physics%26lt%3B%5C%2Fi%26gt%3B%2C%20%26lt%3Bi%26gt%3B58%26lt%3B%5C%2Fi%26gt%3B%2837%29%2C%20375203.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fadfdf2%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fadfdf2%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D2825793%26amp%3Bitem_key%3DI5FKP9A4%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Concentration%20profiles%20of%20OH%20and%20H%3Csub%3E2%3C%5C%2Fsub%3E%20O%3Csub%3E2%3C%5C%2Fsub%3E%20in%20plasma-treated%20water%3A%20influence%20of%20power%2C%20gas%20mixture%20and%20treatment%20distance%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%20Lena%22%2C%22lastName%22%3A%22Sch%5Cu00f6ne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Steffen%22%2C%22lastName%22%3A%22Sch%5Cu00fcttler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Talisha%22%2C%22lastName%22%3A%22Mro%5Cu00df%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Niklas%22%2C%22lastName%22%3A%22Eichstaedt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Judith%22%2C%22lastName%22%3A%22Golda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lars%22%2C%22lastName%22%3A%22Sch%5Cu00fccke%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrew%20R%22%2C%22lastName%22%3A%22Gibson%22%7D%5D%2C%22abstractNote%22%3A%22Plasma%20liquid%20interactions%20are%20important%20for%20a%20range%20of%20applications.%20For%20these%2C%20H2O2%20and%20OH%20represent%20two%20key%20reactive%20species%2C%20whose%20concentrations%20in%20liquids%20need%20to%20be%20controlled%20for%20effective%20application%20outcomes.%20Here%2C%20a%20combination%20of%20gas%20and%20liquid%20simulations%20is%20used%20to%20study%20the%20concentration%20profiles%20of%20H2O2%20and%20OH%20in%20water%20treated%20by%20a%20radio-frequency-driven%20plasma%20jet%2C%20with%20a%20glass%20capillary%20between%20the%20electrodes%2C%20operated%20in%20He%20with%20admixtures%20of%20water%20vapour.%20Simulations%20are%20compared%20with%20measured%20H2O2%20concentrations%20and%20found%20to%20be%20in%20good%20qualitative%20agreement%20as%20plasma%20power%20and%20water%20admixture%20are%20varied.%20Simulation%20results%20show%20that%20the%20concentration%20profiles%20of%20H2O2%20in%20the%20liquid%20are%20mainly%20determined%20by%20transport%2C%20while%20those%20of%20OH%20are%20limited%20by%20reactions%20with%20H2O2%2C%20which%20consumes%20OH.%20For%20a%20given%20plasma%20operating%20condition%2C%20the%20concentration%20and%20penetration%20depth%20of%20H2O2%20increase%20with%20plasma%20treatment%20time%2C%20while%20those%20of%20OH%20tend%20to%20decrease%20because%20of%20the%20increasing%20H2O2%20concentration.%20Plasma%20power%2C%20water%20vapour%20admixture%2C%20and%20the%20distance%20between%20the%20jet%20and%20the%20liquid%20surface%20all%20allow%20for%20the%20concentrations%20of%20H2O2%20and%20OH%20to%20be%20controlled.%20The%20OH%20delivered%20from%20the%20gas%20phase%20to%20the%20liquid%2C%20and%20its%20concentration%20within%20the%20liquid%20are%20strongly%20dependent%20on%20the%20reaction%20pathways%20occurring%20in%20the%20effluent%20region%2C%20such%20that%20the%20trends%20in%20OH%20density%20at%20the%20end%20of%20the%20plasma%20region%20differ%20from%20those%20in%20the%20liquid.%20While%20the%20concentration%20of%20OH%20in%20the%20liquid%20is%20always%20much%20lower%20than%20that%20of%20H2O2%2C%20the%20ratio%20of%20the%20two%20species%20can%20be%20controlled%20over%20orders%20of%20magnitude%20by%20varying%20water%20admixture%20and%20power.%20The%20highest%20selectivity%20to%20OH%20is%20at%20low%20water%20admixtures%2C%20low%20powers%20and%20short%20treatment%20times%2C%20while%20the%20highest%20selectivity%20to%20H2O2%20is%20at%20high%20water%20admixtures%2C%20high%20powers%20and%20long%20treatment%20times.%22%2C%22date%22%3A%222025-09-15%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-6463%5C%2Fadfdf2%22%2C%22citationKey%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2Farticle%5C%2F10.1088%5C%2F1361-6463%5C%2Fadfdf2%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220022-3727%2C%201361-6463%22%2C%22language%22%3A%22en%22%2C%22collections%22%3A%5B%5D%2C%22dateModified%22%3A%222025-09-16T10%3A53%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22YC4TLUH7%22%2C%22library%22%3A%7B%22id%22%3A2825793%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Poggemann%20et%20al.%22%2C%22parsedDate%22%3A%222025-03-31%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%202%3B%20padding-left%3A%201em%3B%20text-indent%3A-1em%3B%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%26gt%3BPoggemann%2C%20H.-F.%2C%20Sch%26%23xFC%3Bttler%2C%20S.%2C%20Sch%26%23xF6%3Bne%2C%20A.%20L.%2C%20Je%26%23xDF%3B%2C%20E.%2C%20Sch%26%23xFC%3Bcke%2C%20L.%2C%20Jacob%2C%20T.%2C%20Gibson%2C%20A.%20R.%2C%20Golda%2C%20J.%2C%20%26amp%3B%20Jung%2C%20C.%20%282025%29.%20Transportation%20behaviour%20of%20OH%20and%20H%26lt%3Bsub%26gt%3B2%26lt%3B%5C%2Fsub%26gt%3B%20O%26lt%3Bsub%26gt%3B2%26lt%3B%5C%2Fsub%26gt%3B%20in%20plasma-treated%20water.%20%26lt%3Bi%26gt%3BJournal%20of%20Physics%20D%3A%20Applied%20Physics%26lt%3B%5C%2Fi%26gt%3B%2C%20%26lt%3Bi%26gt%3B58%26lt%3B%5C%2Fi%26gt%3B%2813%29%2C%20135208.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fadafba%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fadafba%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D2825793%26amp%3Bitem_key%3DYC4TLUH7%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Transportation%20behaviour%20of%20OH%20and%20H%3Csub%3E2%3C%5C%2Fsub%3E%20O%3Csub%3E2%3C%5C%2Fsub%3E%20in%20plasma-treated%20water%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hanna-Friederike%22%2C%22lastName%22%3A%22Poggemann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Steffen%22%2C%22lastName%22%3A%22Sch%5Cu00fcttler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%20Lena%22%2C%22lastName%22%3A%22Sch%5Cu00f6ne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emanuel%22%2C%22lastName%22%3A%22Je%5Cu00df%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lars%22%2C%22lastName%22%3A%22Sch%5Cu00fccke%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Timo%22%2C%22lastName%22%3A%22Jacob%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrew%20R%22%2C%22lastName%22%3A%22Gibson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Judith%22%2C%22lastName%22%3A%22Golda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christoph%22%2C%22lastName%22%3A%22Jung%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20The%20transportation%20of%20plasma-generated%20species%20through%20a%20liquid%20environment%20is%20a%20key%20step%20within%20the%20plasma-driven%20biocatalysis%20process%2C%20but%20is%20also%20of%20great%20importance%20for%20other%20systems%20with%20plasma%5Cu2013liquid%20interfaces.%20The%20aim%20of%20this%20study%20is%20to%20explore%20the%20transportation%20processes%20and%20lifetime%20of%20plasma-generated%20species%20in%20an%20aqueous%20solution.%20Therefore%2C%20a%20combination%20of%20experimental%20methods%2C%20reactive%20molecular%20dynamics%20%28MD%29%20simulations%2C%20and%20reaction%5Cu2013diffusion%20modelling%20was%20used.%20Experimentally%2C%20an%20atmospheric%20pressure%20plasma%20jet%20was%20used%20to%20treat%20an%20aqueous%20sample.%20Convective%20transport%20was%20visualized%20by%20particle%20image%20velocimetry%20in%20the%20plasma-treated%20water.%20Chemiluminescence%20measurements%20of%20OH%20were%20conducted%20by%20the%20use%20of%20luminol%20and%202D-UV-absorption%20spectroscopy%20was%20used%20to%20detect%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20in%20the%20plasma-treated%20water.%20The%20strength%20of%20convective%20transport%20was%20found%20to%20decrease%20with%20the%20gas%20flow%20rate%20through%20the%20jet%2C%20and%20at%20low%20gas%20flows%2C%20an%20effective%20diffusion%20coefficient%20for%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20could%20be%20calculated.%20OH%20was%20mainly%20present%20at%20the%20liquid%20surface%20under%20all%20treatments%20investigated.%20The%20reactive%20MD%20simulations%20form%20the%20basic%20model%20of%20an%20ideal%20system%2C%20where%20all%20transportation%20is%20purely%20diffusion-driven%2C%20and%20molecular%20diffusion%20coefficients%20can%20be%20calculated.%20The%20results%20of%20the%20MD%20simulations%20were%20compared%20with%20the%20experimental%20studies%20to%20gain%20a%20deeper%20understanding%20of%20the%20differences%20between%20the%20ideal%20and%20the%20real%20system.%20To%20bridge%20the%20gap%20between%20the%20time%20scales%20of%20the%20MD%20simulations%20and%20the%20experiments%2C%20a%20kinetic%20model%20was%20used%20to%20understand%20the%20spatio-temporal%20changes%20and%20the%20influence%20of%20transport%20mechanisms%20and%20reaction%20chemistry.%20For%20low%20flow%20rate%20cases%20good%20agreement%20between%20experimental%20measurements%20and%20kinetic%20modelling%20could%20be%20obtained%20when%20the%20experimentally%20measured%20effective%20diffusion%20coefficient%20was%20used%20as%20input%20to%20the%20model.%20The%20differences%20in%20the%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20concentration%20profiles%20in%20the%20liquid%20when%20using%20the%20molecular%20diffusion%20coefficient%20derived%20from%20MD%20and%20the%20effective%20diffusion%20coefficient%20from%20the%20experimental%20measurements%20are%20highlighted.%22%2C%22date%22%3A%222025-03-31%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-6463%5C%2Fadafba%22%2C%22citationKey%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2Farticle%5C%2F10.1088%5C%2F1361-6463%5C%2Fadafba%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220022-3727%2C%201361-6463%22%2C%22language%22%3A%22en%22%2C%22collections%22%3A%5B%5D%2C%22dateModified%22%3A%222025-02-10T09%3A16%3A51Z%22%7D%7D%2C%7B%22key%22%3A%22LYBZFTGK%22%2C%22library%22%3A%7B%22id%22%3A2825793%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Afzal%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%202%3B%20padding-left%3A%201em%3B%20text-indent%3A-1em%3B%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%26gt%3BAfzal%2C%20F.%2C%20%26%23x15A%3Bmi%26%23x142%3Bowicz%2C%20D.%2C%20Kogelheide%2C%20F.%2C%20Sch%26%23xF6%3Bne%2C%20A.%20L.%2C%20Stapelmann%2C%20K.%2C%20Awakowicz%2C%20P.%2C%20%26amp%3B%20Metzler-Nolte%2C%20N.%20%282024%29.%20Chemical%20modification%20of%20selenium-containing%20amino%20acids%20caused%20by%20non-thermal%20dielectric-barrier%20discharge%20atmospheric-pressure%20plasma.%20%26lt%3Bi%26gt%3BRSC%20Advances%26lt%3B%5C%2Fi%26gt%3B%2C%20%26lt%3Bi%26gt%3B14%26lt%3B%5C%2Fi%26gt%3B%2851%29%2C%2038094%26%23x2013%3B38104.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD4RA05754F%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD4RA05754F%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D2825793%26amp%3Bitem_key%3DLYBZFTGK%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Chemical%20modification%20of%20selenium-containing%20amino%20acids%20caused%20by%20non-thermal%20dielectric-barrier%20discharge%20atmospheric-pressure%20plasma%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fahd%22%2C%22lastName%22%3A%22Afzal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dariusz%22%2C%22lastName%22%3A%22%5Cu015ami%5Cu0142owicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Friederike%22%2C%22lastName%22%3A%22Kogelheide%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%20Lena%22%2C%22lastName%22%3A%22Sch%5Cu00f6ne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katharina%22%2C%22lastName%22%3A%22Stapelmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peter%22%2C%22lastName%22%3A%22Awakowicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nils%22%2C%22lastName%22%3A%22Metzler-Nolte%22%7D%5D%2C%22abstractNote%22%3A%22Herein%2C%20we%20present%20an%20investigation%20of%20the%20chemical%20modifications%20of%20selenium-containing%20amino%20acids%20which%20are%20caused%20by%20non-thermal%20plasma%20in%20the%20presence%20of%20redox%20active%20iron%20complexes%20as%20well%20as%20a%20redox%20inert%20zinc%20complex.%5Cn%20%20%20%20%20%20%20%20%20%20%2C%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20Since%20non-thermal%20atmospheric-pressure%20%28%5Cu201ccold%5Cu201d%29%20plasma%20sources%2C%20such%20as%20the%20dielectric-barrier%20discharge%20%28DBD%29%2C%20have%20appeared%20to%20be%20remarkably%20active%20in%20wound%20healing%20medicine%2C%20the%20elucidation%20of%20cold%20plasma%20safety%20and%20possible%20secondary%20undesirable%20effects%20becomes%20of%20paramount%20importance.%20Selenium-containing%20amino%20acids%2C%20which%20are%20commonly%20incorporated%20in%20many%20enzymes%2C%20came%20in%20the%20spotlight%20for%20elucidating%20the%20plasma%20impact%20as%20easily%20oxidizable%20natural%20targets.%20The%20scope%20of%20this%20study%20was%20to%20analyse%20the%20impact%20of%20non-thermal%20plasma%20on%20selenium-containing%20amino%20acids.%20Moreover%2C%20this%20research%20examines%20the%20emerging%20role%20of%20metals%20in%20the%20context%20of%20oxidation%20potency%20of%20reactive%20species%20generated%20by%20plasma.%20The%20dielectric%20barrier%20discharge%20%28DBD%29%20was%20used%20to%20treat%204%20mM%20solutions%20of%20Se-%28methyl%29seleno-%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20l%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20-cysteine%20%281%29%2C%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20l%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20-selenomethionine%20%282%29%20and%20seleno-%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20l%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20-cystine%20%283%29%20for%20varying%20treatment%20times%20to%20investigate%20possible%20degradation%20products.%20In%20this%20study%20we%20used%20two%20redox%20active%20iron%20complexes%20as%20well%20as%20a%20redox%20inert%20zinc%20complex%20in%20order%20to%20compare%20their%20capacity%20to%20affect%20chemical%20modifications%20caused%20by%20plasma.%20The%20solutions%20with%20selenium-containing%20amino%20acids%20after%20plasma%20treatment%20were%20analyzed%20by%20IR%20spectroscopy%2C%20electrospray%20ionization%20mass%20spectrometry%20%28ESI-MS%29%20and%20High%20Performance%20Liquid%20Chromatography%20%28HPLC%29.%20Several%20oxidation%20products%20were%20observed%20as%20a%20consequence%20of%20plasma%20treatment%2C%20namely%3A%20Se-%28methyl%29seleno-%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20l%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20-cysteine%20%281%29%20and%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20l%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20-selenomethionine%20%282%29%20were%20oxidized%20to%20selenoxide%20and%20selendioxide%20derivatives%2C%20wheres%20the%20Se%5Cu2013Se%20dimer%2C%20seleno-%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20l%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20-cystine%20%283%29%2C%20was%20converted%20to%20Se-cysteine%20and%20seleninic%20acid.%20Additionally%20and%20to%20our%20surprise%2C%20redox%20active%20iron%28%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20ii%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%29%20and%20iron%28%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20iii%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%29%20complexes%20as%20well%20as%20the%20non-redox%20active%20zinc%28%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20ii%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%29%20complex%20caused%20the%20same%20oxidation%20pattern%20when%20added%20to%20the%20plasma%20treatment%20mixtures.%20Finally%2C%20a%20comparison%20of%20the%20results%20from%20Se-containing%20amino%20acids%20with%20those%20of%20their%20S-containing%20counterparts%20revealed%20that%20Se-containing%20amino%20acids%20are%20less%20prone%20to%20cold%20plasma%20oxidation%20than%20S-containing%20molecules.%20By%20elucidating%20molecular%20details%20of%20plasma%5Cu2013biomolecule%20interactions%20herein%20we%20aim%20to%20contribute%20to%20a%20better%20understanding%20of%20the%20complex%20beneficial%20medical%20effects%20of%20cold%20plasma%20treatments.%22%2C%22date%22%3A%222024%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2FD4RA05754F%22%2C%22citationKey%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fxlink.rsc.org%5C%2F%3FDOI%3DD4RA05754F%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222046-2069%22%2C%22language%22%3A%22en%22%2C%22collections%22%3A%5B%5D%2C%22dateModified%22%3A%222025-09-16T10%3A33%3A11Z%22%7D%7D%2C%7B%22key%22%3A%22MHDRMRDM%22%2C%22library%22%3A%7B%22id%22%3A2825793%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sch%5Cu00fcttler%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%202%3B%20padding-left%3A%201em%3B%20text-indent%3A-1em%3B%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%26gt%3BSch%26%23xFC%3Bttler%2C%20S.%2C%20Sch%26%23xF6%3Bne%2C%20A.%20L.%2C%20Je%26%23xDF%3B%2C%20E.%2C%20Gibson%2C%20A.%20R.%2C%20%26amp%3B%20Golda%2C%20J.%20%282024%29.%20Production%20and%20transport%20of%20plasma-generated%20hydrogen%20peroxide%20from%20gas%20to%20liquid.%20%26lt%3Bi%26gt%3BPhysical%20Chemistry%20Chemical%20Physics%26lt%3B%5C%2Fi%26gt%3B%2C%2010.1039.D3CP04290A.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD3CP04290A%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD3CP04290A%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D2825793%26amp%3Bitem_key%3DMHDRMRDM%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Production%20and%20transport%20of%20plasma-generated%20hydrogen%20peroxide%20from%20gas%20to%20liquid%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Steffen%22%2C%22lastName%22%3A%22Sch%5Cu00fcttler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%20Lena%22%2C%22lastName%22%3A%22Sch%5Cu00f6ne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emanuel%22%2C%22lastName%22%3A%22Je%5Cu00df%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrew%20R.%22%2C%22lastName%22%3A%22Gibson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Judith%22%2C%22lastName%22%3A%22Golda%22%7D%5D%2C%22abstractNote%22%3A%22The%20transport%20of%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20and%20OH%20from%20an%20atmospheric%20pressure%20plasma%20jet%20to%20a%20liquid%20sample%20are%20investigated%20using%20multiple%20detection%20techniques%20and%20a%20plasma-chemical%20global%20model.%20Scaling%20and%20formation%20pathways%20species%20are%20presented%20and%20discussed.%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%2C%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20In%20this%20work%2C%20the%20transport%20of%20hydroxyl%20radicals%20and%20hydrogen%20peroxide%20from%20a%20humid%20atmospheric%20pressure%20plasma%20jet%20into%20plasma-treated%20liquids%20is%20analysed.%20The%20concentration%20of%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20was%20measured%20by%20a%20spectrophotometric%20approach%20using%20the%20reagent%20ammonium%20metavanadate.%20OH%20was%20measured%20by%20the%20terephthalic%20acid%20dosimeter%20and%20the%20chemiluminescence%20of%20luminol.%20The%20plasma%20jet%20used%20is%20based%20on%20the%20design%20of%20the%20well-investigated%20COST%20reference%20jet%20and%20is%20extended%20by%20a%20capillary%20between%20the%20two%20electrodes.%20In%20addition%20to%20the%20experiments%2C%20the%200-dimensional%20plasma-chemical%20kinetics%20code%20GlobalKin%20was%20used%20to%20analyse%20the%20plasma%20chemistry%20in%20the%20gas%20phase%20in%20more%20detail.%20After%205%20min%20plasma%20treatment%2C%20a%20maximum%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20concentration%20of%201%20mM%20was%20found%20in%20the%20liquid%2C%20while%20the%20OH%20concentration%20was%20a%20factor%2050%20lower.%20The%20concentrations%20of%20both%20species%20in%20the%20liquid%20increased%20with%20plasma%20power%2C%20and%20the%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20concentration%20also%20increased%20with%20the%20humidity%20concentration%20of%20the%20feed%20gas%2C%20while%20the%20OH%20concentration%20first%20increased%20with%20humidity%20admixture%20and%20then%20decreased.%20The%20transport%20of%20both%20species%20could%20be%20controlled%20by%20the%20treatment%20distance%2C%20the%20gas%20flow%20rate%20and%20low%20frequency%20pulsing%20of%20the%20RF%20jet%20in%20such%20a%20way%20that%20the%20selectivity%20towards%20the%20long-lived%20species%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20was%20increased.%20Qualitative%20trends%20in%20the%20simulated%20number%20densities%20of%20gas%20phase%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20O%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%202%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20and%20OH%20at%20the%20location%20of%20the%20gas%5Cu2013liquid%20interface%20fit%20relatively%20well%20to%20the%20experimental%20measurements%20in%20the%20liquid.%22%2C%22date%22%3A%222024%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2FD3CP04290A%22%2C%22citationKey%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fxlink.rsc.org%5C%2F%3FDOI%3DD3CP04290A%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221463-9076%2C%201463-9084%22%2C%22language%22%3A%22en%22%2C%22collections%22%3A%5B%5D%2C%22dateModified%22%3A%222024-02-28T17%3A03%3A46Z%22%7D%7D%2C%7B%22key%22%3A%22FW9W6PMG%22%2C%22library%22%3A%7B%22id%22%3A2825793%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22%5Cu015ami%5Cu0142owicz%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%202%3B%20padding-left%3A%201em%3B%20text-indent%3A-1em%3B%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%26gt%3B%26%23x15A%3Bmi%26%23x142%3Bowicz%2C%20D.%2C%20Kogelheide%2C%20F.%2C%20Sch%26%23xF6%3Bne%2C%20A.%20L.%2C%20Stapelmann%2C%20K.%2C%20Awakowicz%2C%20P.%2C%20%26amp%3B%20Metzler-Nolte%2C%20N.%20%282020%29.%20Catalytic%20oxidation%20of%20small%20organic%20molecules%20by%20cold%20plasma%20in%20solution%20in%20the%20presence%20of%20molecular%20iron%20complexes%26%23x2020%3B.%20%26lt%3Bi%26gt%3BScientific%20Reports%26lt%3B%5C%2Fi%26gt%3B%2C%20%26lt%3Bi%26gt%3B10%26lt%3B%5C%2Fi%26gt%3B%281%29%2C%2021652.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-020-78683-7%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-020-78683-7%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D2825793%26amp%3Bitem_key%3DFW9W6PMG%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Catalytic%20oxidation%20of%20small%20organic%20molecules%20by%20cold%20plasma%20in%20solution%20in%20the%20presence%20of%20molecular%20iron%20complexes%5Cu2020%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dariusz%22%2C%22lastName%22%3A%22%5Cu015ami%5Cu0142owicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Friederike%22%2C%22lastName%22%3A%22Kogelheide%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%20Lena%22%2C%22lastName%22%3A%22Sch%5Cu00f6ne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katharina%22%2C%22lastName%22%3A%22Stapelmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peter%22%2C%22lastName%22%3A%22Awakowicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nils%22%2C%22lastName%22%3A%22Metzler-Nolte%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20The%20plasma-mediated%20decomposition%20of%20volatile%20organic%20compounds%20has%20previously%20been%20investigated%20in%20the%20gas%20phase%20with%20metal%20oxides%20as%20heterogeneous%20catalysts.%20While%20the%20reactive%20species%20in%20plasma%20itself%20are%20well%20investigated%2C%20very%20little%20is%20known%20about%20the%20influence%20of%20metal%20catalysts%20in%20solution.%20Here%2C%20we%20present%20initial%20investigations%20on%20the%20time-dependent%20plasma-supported%20oxidation%20of%20benzyl%20alcohol%2C%20benzaldehyde%20and%20phenol%20in%20the%20presence%20of%20molecular%20iron%20complexes%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20in%20solution%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20.%20Products%20were%20identified%20by%20HPLC%2C%20ESI-MS%2C%20FT-IR%2C%20and%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%24%24%5E%7B1%7D%5C%5Chbox%20%7BH%20NMR%7D%24%24%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%201%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20H%20NMR%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20spectroscopy.%20Compared%20to%20metal-free%20oxidation%20of%20the%20substrates%2C%20which%20is%20caused%20by%20reactive%20oxygen%20species%20and%20leads%20to%20a%20mixture%20of%20products%2C%20the%20metal-mediated%20reactions%20lead%20to%20one%20product%20cleanly%2C%20and%20faster%20than%20in%20the%20metal-free%20reactions.%20Most%20noteworthy%2C%20even%20catalytic%20amounts%20of%20metal%20complexes%20induce%20these%20clean%20transformations.%20The%20findings%20described%20here%20bear%20important%20implications%20for%20plasma-supported%20industrial%20waste%20transformations%2C%20as%20well%20as%20for%20plasma-mediated%20applications%20in%20biomedicine%2C%20given%20the%20fact%20that%20iron%20is%20the%20most%20abundant%20redox-active%20metal%20in%20the%20human%20body.%22%2C%22date%22%3A%2212%5C%2F2020%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41598-020-78683-7%22%2C%22citationKey%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nature.com%5C%2Farticles%5C%2Fs41598-020-78683-7%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222045-2322%22%2C%22language%22%3A%22en%22%2C%22collections%22%3A%5B%5D%2C%22dateModified%22%3A%222021-07-19T14%3A25%3A08Z%22%7D%7D%5D%7D<\/span>\n\n\t\t\t\t<div id=\"zp-ID-492-2825793-RWLZGH2K\" data-zp-author-date='Grimm-et-al.-2026-01-23' data-zp-date-author='2026-01-23-Grimm-et-al.' data-zp-date='2026-01-23' data-zp-year='2026' data-zp-itemtype='journalArticle' class=\"zp-Entry zpSearchResultsItem\">\n<div class=\"csl-bib-body\" style=\"line-height: 2; padding-left: 1em; text-indent:-1em;\">\n  <div class=\"csl-entry\">Grimm, F., Gembus, J.-L., Sch\u00f6ne, J., Awakowicz, P., Sch\u00fccke, L., & Gibson, A. R. (2026). Electron and gas temperature-driven chemistry during microdischarges formed in water vapor bubbles. <i>Journal of Physics D: Applied Physics<\/i>, <i>59<\/i>(3), 035201. <a class='zp-DOIURL' href='https:\/\/doi.org\/10.1088\/1361-6463\/ae20a1'>https:\/\/doi.org\/10.1088\/1361-6463\/ae20a1<\/a> <a title='Cite in RIS Format' class='zp-CiteRIS' data-zp-cite='api_user_id=2825793&item_key=RWLZGH2K' href='javascript:void(0);'>Cite<\/a> <\/div>\n<\/div>\n\t\t\t\t<\/div><!-- .zp-Entry .zpSearchResultsItem -->\t\t\t\t<div id=\"zp-ID-492-2825793-I5FKP9A4\" data-zp-author-date='Sch\u00f6ne-et-al.-2025-09-15' data-zp-date-author='2025-09-15-Sch\u00f6ne-et-al.' data-zp-date='2025-09-15' data-zp-year='2025' data-zp-itemtype='journalArticle' class=\"zp-Entry zpSearchResultsItem\">\n<div class=\"csl-bib-body\" style=\"line-height: 2; padding-left: 1em; text-indent:-1em;\">\n  <div class=\"csl-entry\">Sch\u00f6ne, A. L., Sch\u00fcttler, S., Mro\u00df, T., Eichstaedt, N., Golda, J., Sch\u00fccke, L., & Gibson, A. R. (2025). Concentration profiles of OH and H<sub>2<\/sub> O<sub>2<\/sub> in plasma-treated water: influence of power, gas mixture and treatment distance. <i>Journal of Physics D: Applied Physics<\/i>, <i>58<\/i>(37), 375203. <a class='zp-DOIURL' href='https:\/\/doi.org\/10.1088\/1361-6463\/adfdf2'>https:\/\/doi.org\/10.1088\/1361-6463\/adfdf2<\/a> <a title='Cite in RIS Format' class='zp-CiteRIS' data-zp-cite='api_user_id=2825793&item_key=I5FKP9A4' href='javascript:void(0);'>Cite<\/a> <\/div>\n<\/div>\n\t\t\t\t<\/div><!-- .zp-Entry .zpSearchResultsItem -->\t\t\t\t<div id=\"zp-ID-492-2825793-YC4TLUH7\" data-zp-author-date='Poggemann-et-al.-2025-03-31' data-zp-date-author='2025-03-31-Poggemann-et-al.' data-zp-date='2025-03-31' data-zp-year='2025' data-zp-itemtype='journalArticle' class=\"zp-Entry zpSearchResultsItem\">\n<div class=\"csl-bib-body\" style=\"line-height: 2; padding-left: 1em; text-indent:-1em;\">\n  <div class=\"csl-entry\">Poggemann, H.-F., Sch\u00fcttler, S., Sch\u00f6ne, A. L., Je\u00df, E., Sch\u00fccke, L., Jacob, T., Gibson, A. R., Golda, J., & Jung, C. (2025). Transportation behaviour of OH and H<sub>2<\/sub> O<sub>2<\/sub> in plasma-treated water. <i>Journal of Physics D: Applied Physics<\/i>, <i>58<\/i>(13), 135208. <a class='zp-DOIURL' href='https:\/\/doi.org\/10.1088\/1361-6463\/adafba'>https:\/\/doi.org\/10.1088\/1361-6463\/adafba<\/a> <a title='Cite in RIS Format' class='zp-CiteRIS' data-zp-cite='api_user_id=2825793&item_key=YC4TLUH7' href='javascript:void(0);'>Cite<\/a> <\/div>\n<\/div>\n\t\t\t\t<\/div><!-- .zp-Entry .zpSearchResultsItem -->\t\t\t\t<div id=\"zp-ID-492-2825793-LYBZFTGK\" data-zp-author-date='Afzal-et-al.-2024' data-zp-date-author='2024-Afzal-et-al.' data-zp-date='2024' data-zp-year='2024' data-zp-itemtype='journalArticle' class=\"zp-Entry zpSearchResultsItem\">\n<div class=\"csl-bib-body\" style=\"line-height: 2; padding-left: 1em; text-indent:-1em;\">\n  <div class=\"csl-entry\">Afzal, F., \u015ami\u0142owicz, D., Kogelheide, F., Sch\u00f6ne, A. L., Stapelmann, K., Awakowicz, P., & Metzler-Nolte, N. (2024). Chemical modification of selenium-containing amino acids caused by non-thermal dielectric-barrier discharge atmospheric-pressure plasma. <i>RSC Advances<\/i>, <i>14<\/i>(51), 38094\u201338104. <a class='zp-DOIURL' href='https:\/\/doi.org\/10.1039\/D4RA05754F'>https:\/\/doi.org\/10.1039\/D4RA05754F<\/a> <a title='Cite in RIS Format' class='zp-CiteRIS' data-zp-cite='api_user_id=2825793&item_key=LYBZFTGK' href='javascript:void(0);'>Cite<\/a> <\/div>\n<\/div>\n\t\t\t\t<\/div><!-- .zp-Entry .zpSearchResultsItem -->\t\t\t\t<div id=\"zp-ID-492-2825793-MHDRMRDM\" data-zp-author-date='Sch\u00fcttler-et-al.-2024' data-zp-date-author='2024-Sch\u00fcttler-et-al.' data-zp-date='2024' data-zp-year='2024' data-zp-itemtype='journalArticle' class=\"zp-Entry zpSearchResultsItem\">\n<div class=\"csl-bib-body\" style=\"line-height: 2; padding-left: 1em; text-indent:-1em;\">\n  <div class=\"csl-entry\">Sch\u00fcttler, S., Sch\u00f6ne, A. L., Je\u00df, E., Gibson, A. R., & Golda, J. (2024). Production and transport of plasma-generated hydrogen peroxide from gas to liquid. <i>Physical Chemistry Chemical Physics<\/i>, 10.1039.D3CP04290A. <a class='zp-DOIURL' href='https:\/\/doi.org\/10.1039\/D3CP04290A'>https:\/\/doi.org\/10.1039\/D3CP04290A<\/a> <a title='Cite in RIS Format' class='zp-CiteRIS' data-zp-cite='api_user_id=2825793&item_key=MHDRMRDM' href='javascript:void(0);'>Cite<\/a> <\/div>\n<\/div>\n\t\t\t\t<\/div><!-- .zp-Entry .zpSearchResultsItem -->\t\t\t\t<div id=\"zp-ID-492-2825793-FW9W6PMG\" data-zp-author-date='\u015ami\u0142owicz-et-al.-2020' data-zp-date-author='2020-\u015ami\u0142owicz-et-al.' data-zp-date='2020' data-zp-year='2020' data-zp-itemtype='journalArticle' class=\"zp-Entry zpSearchResultsItem\">\n<div class=\"csl-bib-body\" style=\"line-height: 2; padding-left: 1em; text-indent:-1em;\">\n  <div class=\"csl-entry\">\u015ami\u0142owicz, D., Kogelheide, F., Sch\u00f6ne, A. L., Stapelmann, K., Awakowicz, P., & Metzler-Nolte, N. (2020). Catalytic oxidation of small organic molecules by cold plasma in solution in the presence of molecular iron complexes\u2020. <i>Scientific Reports<\/i>, <i>10<\/i>(1), 21652. <a class='zp-DOIURL' href='https:\/\/doi.org\/10.1038\/s41598-020-78683-7'>https:\/\/doi.org\/10.1038\/s41598-020-78683-7<\/a> <a title='Cite in RIS Format' class='zp-CiteRIS' data-zp-cite='api_user_id=2825793&item_key=FW9W6PMG' href='javascript:void(0);'>Cite<\/a> <\/div>\n<\/div>\n\t\t\t\t<\/div><!-- .zp-Entry .zpSearchResultsItem -->\n\t\t\t<\/div><!-- .zp-zp-SEO-Content -->\n\t\t<\/div><!-- .zp-List -->\n\t<\/div><!--.zp-Zotpress-->","protected":false},"excerpt":{"rendered":"<p>Researcher AddressRuhr-Uni\u00adver\u00adsi\u00adt\u00e4t Bo\u00adchumFakult\u00e4t f\u00fcr Elektrotechnik und InformationstechnikBiomedizinsch Angewandte PlasmatechnikUni\u00adver\u00adsi\u00adt\u00e4ts\u00adstra\u00ad\u00dfe 150D-44801 Bo\u00adchum, Germany RoomID 1\/531 Phone+49 234 32 28872 Emailschoene(at)aept.rub.de Publications<\/p>","protected":false},"author":3,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-492","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/pages\/492","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/comments?post=492"}],"version-history":[{"count":2,"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/pages\/492\/revisions"}],"predecessor-version":[{"id":494,"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/pages\/492\/revisions\/494"}],"wp:attachment":[{"href":"https:\/\/aept.blogs.ruhr-uni-bochum.de\/de\/wp-json\/wp\/v2\/media?parent=492"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}